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Thermodynamic temperature is the absolute measure of temperature and is one of the principal parameters of thermodynamics. Thermodynamic temperature is defined by the third law of thermodynamics in which the theoretically lowest temperature is the null or zero point. At this point, absolute zero, the particle constituents of matter have minimal motion and can become no colder.〔Rankine, W.J.M., "A manual of the steam engine and other prime movers", Richard Griffin and Co., London (1859), p. 306-7〕〔William Thomson, 1st Baron Kelvin, "Heat", Adam and Charles Black, Edinburgh (1880), p. 39〕 In the quantum-mechanical description, matter at absolute zero is in its ground state, which is its state of lowest energy. Thermodynamic temperature is often also called absolute temperature, for two reasons: one, proposed by Kelvin, that it does not depend on the properties of a particular material; two that it refers to an absolute zero according to the properties of the ideal gas. The International System of Units specifies a particular scale for thermodynamic temperature. It uses the Kelvin scale for measurement and selects the triple point of water at as the fundamental fixing point. Other scales have been in use historically. The Rankine scale, using the degree Fahrenheit as its unit interval, is still in use as part of the English Engineering Units in the United States in some engineering fields. ITS-90 gives a practical means of estimating the thermodynamic temperature to a very high degree of accuracy. Roughly, the temperature of a body at rest is a measure of the mean of the energy of the translational, vibrational and rotational motions of matter's particle constituents, such as molecules, atoms, and subatomic particles. The full variety of these kinetic motions, along with potential energies of particles, and also occasionally certain other types of particle energy in equilibrium with these, make up the total internal energy of a substance. Internal energy is loosely called the heat energy or thermal energy in conditions when no work is done upon the substance by its surroundings, or by the substance upon the surroundings. Internal energy may be stored in a number of ways within a substance, each way constituting a "degree of freedom". At equilibrium, each degree of freedom will have on average the same energy: where is the Boltzmann constant, unless that degree of freedom is in the quantum regime. The internal degrees of freedom (rotation, vibration, etc.) may be in the quantum regime at room temperature, but the translational degrees of freedom will be in the classical regime except at extremely low temperatures (fractions of kelvins) and it may be said that, for most situations, the thermodynamic temperature is specified by the average translational kinetic energy of the particles. == Overview == Temperature is a measure of the random submicroscopic motions and vibrations of the particle constituents of matter. These motions comprise the internal energy of a substance. More specifically, the thermodynamic temperature of any bulk quantity of matter is the measure of the average kinetic energy per classical (i.e., non-quantum) degree of freedom of its constituent particles. "Translational motions" are almost always in the classical regime. Translational motions are ordinary, whole-body movements in three-dimensional space in which particles move about and exchange energy in collisions. ''Figure 1'' below shows translational motion in gases; ''Figure 4'' below shows translational motion in solids. Thermodynamic temperature's null point, absolute zero, is the temperature at which the particle constituents of matter are as close as possible to complete rest; that is, they have minimal motion, retaining only quantum mechanical motion.〔 While scientists are achieving temperatures ever closer to absolute zero, they can not fully achieve a state of ''zero'' temperature. However, even if scientists could remove ''all'' kinetic thermal energy from matter, quantum mechanical ''zero-point energy'' (ZPE) causes particle motion that can never be eliminated. Encyclopædia Britannica Online (defines zero-point ) energy as the "vibrational energy that molecules retain even at the absolute zero of temperature". ZPE is the result of all-pervasive energy fields in the vacuum between the fundamental particles of nature; it is responsible for the Casimir effect and other phenomena. See ''(Zero Point Energy and Zero Point Field )''. See also ''(Solid Helium )'' by the University of Alberta's Department of Physics to learn more about ZPE's effect on Bose–Einstein condensates of helium. Although absolute zero (''T''=0) is not a state of zero molecular motion, it ''is ''the point of zero temperature and, in accordance with the Boltzmann constant, is also the point of zero particle kinetic energy and zero kinetic velocity. To understand how atoms can have zero kinetic velocity and simultaneously be vibrating due to ZPE, consider the following thought experiment: two ''T''=0 helium atoms in zero gravity are carefully positioned and observed to have an average separation of 620 pm between them (a gap of ten atomic diameters). It's an "average" separation because ZPE causes them to jostle about their fixed positions. Then one atom is given a kinetic kick of precisely 83 yoctokelvins (1 yK = ). This is done in a way that directs this atom's velocity vector at the other atom. With 83 yK of kinetic energy between them, the 620 pm gap through their common barycenter would close at a rate of 719 pm/s and they would collide after 0.862 second. This is the same speed as shown in the ''Fig. 1 ''animation above. Before being given the kinetic kick, both ''T''=0 atoms had zero kinetic energy and zero kinetic velocity because they could persist indefinitely in that state and relative orientation even though both were being jostled by ZPE. At ''T''=0, no kinetic energy is available for transfer to other systems. The Boltzmann constant and its related formulas describe the realm of particle kinetics and velocity vectors whereas ZPE is an energy field that jostles particles in ways described by the mathematics of quantum mechanics. In atomic and molecular collisions in gases, ZPE introduces a degree of ''chaos'', i.e., unpredictability, to rebound kinetics; it is as likely that there will be ''less'' ZPE-induced particle motion after a given collision as ''more.'' This random nature of ZPE is why it has no net effect upon either the pressure or volume of any ''bulk quantity'' (a statistically significant quantity of particles) of ''T''>0 K gases. However, in ''T''=0 condensed matter; e.g., solids and liquids, ZPE causes inter-atomic jostling where atoms would otherwise be perfectly stationary. Inasmuch as the real-world effects that ZPE has on substances can vary as one alters a thermodynamic system (for example, due to ZPE, helium won't freeze unless under a pressure of at least 25 bar or 2.5 MPa), ZPE is very much a form of thermal energy and may properly be included when tallying a substance's internal energy. Note too that absolute zero serves as the baseline atop which thermodynamics and its equations are founded because they deal with the exchange of thermal energy between ''"systems"'' (a plurality of particles and fields modeled as an average). Accordingly, one may examine ZPE-induced particle motion ''within'' a system that is at absolute zero but there can never be a net outflow of thermal energy from such a system. Also, the peak emittance wavelength of black-body radiation shifts to infinity at absolute zero; indeed, a peak no longer exists and black-body photons can no longer escape. Because of ZPE, however, ''virtual'' photons are still emitted at ''T''=0. Such photons are called "virtual" because they can't be intercepted and observed. Furthermore, this ''zero-point radiation'' has a unique ''zero-point spectrum.'' However, even though a ''T''=0 system emits zero-point radiation, no net heat flow ''Q'' out of such a system can occur because if the surrounding environment is at a temperature greater than ''T''=0, heat will flow inward, and if the surrounding environment is at ''T''=0, there will be an equal flux of ZP radiation both inward and outward. A similar ''Q ''equilibrium exists at ''T''=0 with the ZPE-induced spontaneous emission of photons (which is more properly called a ''stimulated'' emission in this context). The graph at upper right illustrates the relationship of absolute zero to zero-point energy. The graph also helps in the understanding of how zero-point energy got its name: it is the vibrational energy matter retains at the ''zero kelvin point''. (''Derivation of the classical electromagnetic zero-point radiation spectrum via a classical thermodynamic operation involving van der Waals forces'' ), Daniel C. Cole, Physical Review A, 42 (1990) 1847.〕 Zero kinetic energy remains in a substance at absolute zero (see ''Thermal energy at absolute zero'', below). Throughout the scientific world where measurements are made in SI units, thermodynamic temperature is measured in kelvins (symbol: K). Many engineering fields in the U.S. however, measure thermodynamic temperature using the Rankine scale. By (international agreement ), the unit ''kelvin'' and its scale are defined by two points: absolute zero, and the triple point of Vienna Standard Mean Ocean Water (water with a specified blend of hydrogen and oxygen isotopes). Absolute zero, the lowest possible temperature, is defined as being precisely 0 K ''and'' −273.15 °C. The triple point of water is defined as being precisely 273.16 K ''and'' 0.01 °C. This definition does three things: # It fixes the magnitude of the kelvin unit as being precisely 1 part in 273.16 parts the difference between absolute zero and the triple point of water; # It establishes that one kelvin has precisely the same magnitude as a one-degree increment on the Celsius scale; and # It establishes the difference between the two scales' null points as being precisely 273.15 kelvins (0 K = −273.15 °C and 273.16 K = 0.01 °C). Temperatures expressed in kelvins are converted to degrees Rankine simply by multiplying by 1.8 as follows: ''T''°R = 1.8''T''K, where ''T''K and ''T''°R are temperatures in kelvin and degrees Rankine respectively. Temperatures expressed in degrees Rankine are converted to kelvins by ''dividing'' by 1.8 as follows: ''T''K = . 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「thermodynamic temperature」の詳細全文を読む スポンサード リンク
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